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By Dieter Enders, Karl-Erich Jaeger, Günter Helmchen

ISBN-10: 3527314733

ISBN-13: 9783527314737

Edited through of the prime researchers within the box, this e-book offers a deep, interdisciplinary perception into stoichiometric and catalytic reactions during this consistently increasing zone. A plethora of best German scientists with a world acceptance covers numerous features, from classical natural chemistry to method improvement, and from the theoretical history to organic tools utilizing enzymes. during the concentration is at the improvement of recent artificial tools in uneven synthesis, the synthesis of common and bioactive compounds and the newest advancements in either chemical and organic tools of catalysis, in addition to the research of precise technical and biotechnical elements.

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Chem. Soc. 1993, 115, 10 139; g) N. Shida, C. Kabuto, T. Niwa, T. Ebata, Y. Yamamoto J. Org. Chem. 1994, 59, 4068. 19 F. Loydl, Justus Liebigs Ann. Chem. 1878, 192, 80. 20 T. Komnenos, Justus Liebigs Ann. Chem. 1883, 218, 145. 21 a) L. Claisen, Justus Liebigs Ann. Chem. 1883, 218, 170; b) L. Claisen, Justus Liebigs Ann. Chem. 1887, 35, 413. 22 a) A. Michael, J. Prakt. Chem. 1887, 35, 349; b) A. Michael, Am. Chem. J. 1887, 9, 112; c) A. Michael, O. Schulthess, J. Prakt. Chem. 1892, 45, 55; d) A.

2 Asymmetric Nucleophilic Alkenoylation of Aldehydes α -Hydroxyenones F are versatile building blocks, structural subunits of many natural products, and suitable precursors for Nazarov cyclizations. 17 indicates that the targets F can be traced back to the addition of a synthetic equivalent of the α ,β -unsaturated acyl anion G to aldehydes H. Toward this goal, a great deal of attention has been devoted to the development of both achiral and chiral equivalents of G, such as heteroatomstabilized allylic anions [45], organometallic zirconium [46], or vinyl-lithium reagents [47].

Eng. Prog. 1979, 75, 73. a) S. D. Perera, B. L. Shaw, J. Organomet. Chem. 1991, 402, 133; b) D. A. Knight, D. J. Cole-Hamilton, D. C. Cupertino, J. Chem. , Dalton Trans. 1990, 3051; c) H. Brunner, A. Sicheneder, Angew. Chem. 1988, 100, 730; Angew. Chem. Int. Ed. Engl. 1988, 27, 718; d) H. B. Kagan, M. Tahar, J. C. Fiaud, Tetrahedron Lett. 1991, 32, 5959; e) T. Hayashi, Y. Uozomi, Pure Appl. Chem. 1992, 64, 1911; f) Y. Uozumi, A. -Y. Lee, T. Hayashi, J. Org. Chem. 1993, 58, 1945; g) N. Sakai, S.

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Asymmetric Synthesis with Chemical and Biological Methods by Dieter Enders, Karl-Erich Jaeger, Günter Helmchen

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